All kick-off times in GMT.
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- Sat, Nov 10, 2012
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| FT | Inverness Caledonian Thistle | 1 - 1 | Heart of Midlothian |
| FT | Kilmarnock | 3 - 0 | Ross County |
| FT | Motherwell | 1 - 1 | Dundee |
| FT | St Mirren | 1 - 4 | Aberdeen |
| FT | Bonnyrigg Rose | 0 - 6 | Brechin City |
| FT | Arbroath | 3 - 1 | Inverurie Locos |
| FT | Nairn County | 2 - 3 | Forfar Athletic |
| FT | Queen's Park | 0 - 4 | Stranraer |
| FT | Cowdenbeath | 0 - 1 | Dumbarton |
| FT | Greenock Morton | 0 - 1 | Hamilton Academical |
| FT | Partick Thistle | 5 - 1 | Dunfermline Athletic |
| FT | Raith Rovers | 2 - 1 | Falkirk |
| FT | Annan Athletic | 5 - 2 | Stirling Albion |
| FT | Clyde | 1 - 2 | Montrose |
| FT | Elgin City | 3 - 1 | Berwick Rangers |
| FT | Rangers | 2 - 0 | Peterhead |
| FT | Rayo Vallecano | 3 - 2 | Celta Vigo |
| FT | Espanyol | 0 - 3 | Osasuna |
| FT | Real Zaragoza | 5 - 3 | Deportivo La Coruña |
| FT | Malaga | 1 - 2 | Real Sociedad |
| FT | Girona | 1 - 0 | Racing Santander |
| FT | Barcelona B | 3 - 3 | Numancia |
| FT | Guadalajara | 2 - 1 | Sporting Gijon |
| FT | CD Sabadell | 1 - 0 | Huesca |
| FT | Xerez | 0 - 0 | Elche |
| FT | Bayern Munich | 2 - 0 | Eintracht Frankfurt |
| FT | FC Augsburg | 1 - 3 | Borussia Dortmund |
| FT | Fortuna Düsseldorf | 1 - 1 | TSG Hoffenheim |
| FT | SC Freiburg | 0 - 0 | Hamburg SV |
| FT | Schalke 04 | 2 - 1 | Werder Bremen |
| FT | Lille | 1 - 0 | Brest |
| FT | Bastia | 2 - 3 | Valenciennes |
| FT | St Etienne | 2 - 0 | Troyes |
| FT | Stade de Reims | 1 - 2 | Evian Thonon Gaillard |
| FT | Toulouse | 2 - 4 | AC Ajaccio |
| FT | RKC Waalwijk | 4 - 0 | FC Utrecht |
| FT | ADO Den Haag | 2 - 2 | AZ Alkmaar |
| FT | VVV Venlo | 4 - 1 | Willem II Tilburg |
| FT | NEC Nijmegen | 3 - 2 | SC Heracles Almelo |
| FT | Dinamo Moscow | 2 - 0 | Alania Vladikavkaz |
| FT | Terek Grozny | 2 - 1 | Mordovia Saransk |
| FT | Kuban Krasnodar | 1 - 3 | CSKA Moscow |
| FT | Kasimpasa | 1 - 1 | Antalyaspor |
| FT | Karabukspor | 3 - 1 | Istanbul Buyuksehir BSK |
| FT | Trabzonspor | 3 - 1 | Akhisar Belediye |
| FT | Cercle Brugge KSV | 2 - 2 | KAA Gent |
| FT | Lierse SK | 1 - 3 | Germinal Beerschot |
| FT | OH Leuven | 0 - 0 | KV Kortrijk |
| FT | Waasland-Beveren | 0 - 0 | Royal Charleroi SC |
| FT | Zulte-Waregem | 1 - 1 | KV Mechelen |
| FT | FC Trenkwalder Admira | 1 - 2 | SK Sturm Graz |
| FT | FC Wacker Tirol | 0 - 3 | Austria Vienna |
| FT | SV Josko Ried | 6 - 1 | SV Mattersburg |
| FT | Ballymena | 2 - 1 | Crusaders |
| FT | Cliftonville | 3 - 0 | Linfield |
| FT | Glenavon | 4 - 2 | Donegal Celtic |
| FT | Glentoran | 2 - 1 | Dungannon Swifts |
| FT | Lisburn Distillery | 1 - 1 | Coleraine |
| FT | Portadown | 2 - 1 | Ballinamallard Utd |
| FT | San Lorenzo | 4 - 0 | All Boys |
| FT | River Plate | 2 - 0 | Unión de Santa Fe |
| FT | Estudiantes La Plata | 3 - 1 | Atletico Rafaela |
| FT | Bella Vista | 0 - 1 | Cerro Largo |
| FT | Central Español | 1 - 0 | Danubio F.C. |
| FT | Fénix | 1 - 3 | Defensor Sporting |
| FT | River Plate | 0 - 1 | Cerro |
| FT | Juventud | 2 - 1 | Liverpool |
| FT | El Tanque Sisley | 2 - 2 | Progreso |
| FT | Patriotas F.C. | 0 - 2 | Millonarios |
| FT | Atlético Huila | 2 - 3 | Itagüí |
| FT | Atlético Junior | 2 - 0 | Once Caldas |
| FT | Envigado | 2 - 0 | Deportes Tolima |
| FT | La Equidad | 1 - 1 | Deportivo Cali |
| FT | Atlético Nacional | 2 - 1 | Real Cartagena |
| Group A | |||
|---|---|---|---|
| FT | Inti Gas Deportes | 0 - 1 | Club Sportivo Cienciano |
| FT | San Martin | 0 - 1 | Universitario de Deportes |
| Group B | |||
| FT | Juan Aurich | 1 - 1 | León de Huánuco |
| FT | César Vallejo | 0 - 0 | Alianza Lima |
| FT | Real Espor | 2 - 1 | Atlético Venezuela |
| FT | Sydney FC | 2 - 3 | Melbourne Victory |
| FT | Wellington Phoenix FC | 0 - 1 | Central Coast Mariners |
| FT | Adelaide United | 1 - 1 | Perth Glory |
| FT | Pretoria Univ | 1 - 1 | Mamelodi Sundowns |
| FT | Silver Stars | 2 - 1 | Bidvest Wits |
| FT | Golden Arrows | 0 - 1 | Maritzburg Utd |
| FT | Orlando Pirates | 1 - 0 | Free State Stars |
| FT | SuperSport United | 1 - 2 | Kaizer Chiefs |
| FT | Universidad de El Salvador | 3 - 3 | Alianza FC |
| FT | Aguila | 1 - 1 | CD FAS |