All kick-off times in GMT.
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- Sun, Nov 11, 2012
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| FT | Manchester City | 2 - 1 | Tottenham Hotspur |
| FT | Newcastle United | 0 - 1 | West Ham United |
| FT | Chelsea | 1 - 1 | Liverpool |
| FT | Real Valladolid | 1 - 1 | Valencia |
| FT | Athletic Bilbao | 2 - 1 | Sevilla FC |
| FT | Mallorca | 2 - 4 | Barcelona |
| FT | Atletico Madrid | 2 - 0 | Getafe |
| FT | Levante | 1 - 2 | Real Madrid |
| FT | Hercules | 0 - 2 | Las Palmas |
| FT | Villarreal | 1 - 1 | Murcia |
| FT | AD Alcorcon | 2 - 1 | Lugo |
| FT | Almeria | 0 - 0 | Mirandes |
| FT | Ponferradina | 3 - 5 | Cordoba |
| FT | Palermo | 2 - 0 | Sampdoria |
| FT | AC Milan | 1 - 3 | Fiorentina |
| FT | Chievo Verona | 2 - 2 | Udinese |
| FT | Genoa | 2 - 4 | Napoli |
| FT | Lazio | 3 - 2 | AS Roma |
| FT | Parma | 0 - 0 | Siena |
| FT | Torino | 1 - 0 | Bologna |
| FT | Atalanta | 3 - 2 | Internazionale |
| FT | VfL Wolfsburg | 3 - 1 | Bayer Leverkusen |
| FT | SpVgg Greuther Furth | 2 - 4 | Borussia Monchengladbach |
| FT | VfB Stuttgart | 2 - 4 | Hannover 96 |
| FT | Energie Cottbus | 2 - 0 | Dynamo Dresden |
| FT | FC Ingolstadt 04 | 4 - 2 | SSV Jahn Regensburg |
| FT | FSV Frankfurt | 0 - 1 | TSV 1860 Munich |
| FT | Vitesse Arnhem | 0 - 0 | Twente Enschede |
| FT | Feyenoord Rotterdam | 5 - 2 | Roda JC Kerkrade |
| FT | PEC Zwolle | 2 - 4 | Ajax Amsterdam |
| FT | PSV Eindhoven | 5 - 1 | Heerenveen |
| FT | Estoril | 2 - 0 | Moreirense |
| FT | Olhanense | 1 - 0 | Beira Mar |
| FT | FC Porto | 2 - 1 | Academica de Coimbra |
| FT | Rio Ave | 0 - 1 | Benfica |
| FT | Sporting Lisbon | 1 - 0 | Braga |
| FT | Lokomotiv Moscow | 1 - 1 | Anzhi Makhachkala |
| FT | FK Rubin Kazan | 2 - 0 | PFK Samara Kryliya Sovetov |
| FT | Volga Nizhny Novgorod | 1 - 2 | Zenit St Petersburg |
| FT | Spartak Moscow | 2 - 0 | Krasnodar |
| FT | Gaziantepspor | 2 - 3 | Genclerbirligi |
| FT | Mersin Idmanyurdu | 1 - 1 | Galatasaray |
| FT | Elazigspor | 0 - 4 | Kayserispor |
| FT | Fenerbahce | 2 - 1 | Orduspor |
| FT | Atromitos | 1 - 0 | Panionios |
| FT | Panthrakikos | 1 - 0 | Asteras Tripoli |
| FT | PAOK Salonika | 2 - 0 | Platanias |
| FT | AEK Athens | 0 - 4 | Olympiakos |
| FT | Lanús | 4 - 1 | Tigre |
| FT | San Martín de San Juan | 0 - 0 | Independiente |
| FT | Colón de Santa Fe | 0 - 0 | Boca Juniors |
| FT | Racing Club | 0 - 0 | Arsenal de Sarandí |
| FT | CR Vasco da Gama | 1 - 1 | Atlético MG |
| FT | Gremio | 2 - 1 | São Paulo |
| FT | Palmeiras | 2 - 3 | Fluminense FC |
| FT | AA Ponte Preta | 1 - 0 | Internacional |
| FT | Cruzeiro | 3 - 1 | Bahia |
| FT | Figueirense FC | 1 - 1 | Sport |
| FT | Náutico | 0 - 1 | Flamengo |
| FT | Deportes Quindío | 1 - 3 | Independiente Medellín |
| FT | Deportivo Pasto | 2 - 1 | Cúcuta Deportivo |
| FT | Independiente Santa Fe | 1 - 0 | Boyacá Chicó FC |
| Group A | |||
|---|---|---|---|
| FT | Cobresol | 4 - 0 | Sport Huancayo |
| FT | José Gálvez | 3 - 1 | Sporting Cristal |
| Group B | |||
| FT | Real Garcilaso | 3 - 0 | Sport Boys |
| FT | Melgar FBC | 3 - 0 | Unión Comercio |
| FT | Sp. Carapeguá | 2 - 0 | Independiente CG |
| FT | Rubio Ñú | 1 - 2 | Cerro Porteño |
| FT | Guaraní | 0 - 1 | Nacional |
| FT | Club Deportivo Cuenca | 1 - 1 | Manta F.C. |
| FT | El Nacional | 2 - 1 | Macará |
| FT | Independiente Terán | 2 - 0 | Emelec |
| FT | Tec. Universitario | 0 - 0 | Deportivo Quito |
| FT | Liga de Loja | 2 - 1 | Olmedo |
| FT | Barcelona | 1 - 0 | LDU Quito |
| FT | Dep. Petare | 4 - 1 | Caracas F.C. |
| FT | Llaneros | 3 - 3 | CD Lara |
| FT | Trujillanos | 1 - 1 | Zulia |
| FT | Yaracuyanos | 0 - 1 | Portuguesa |
| FT | A.C. Mineros | 1 - 1 | Aragua |
| FT | Estudiantes de Mérida | 0 - 0 | Atlético Vigía |
| FT | Monagas SC | 2 - 2 | Anzoátegui |
| FT | Puntarenas | 1 - 0 | Cartagines |
| FT | Saprissa | 2 - 1 | San Carlos |
| FT | Carmelita | 2 - 2 | Belen |
| FT | Club Sport Uruguay | 0 - 0 | Limon |
| FT | Perez Zeledon | 4 - 1 | Santos |
| FT | C.D.Real Sociedad | 0 - 2 | Victoria |
| FT | CD Motagua | 0 - 0 | Atletico Choloma |
| FT | Deportes Savio | 1 - 0 | Marathon |
| FT | Real Espana | 1 - 1 | Platense |
| FT | Vida | 1 - 3 | Olimpia |