All kick-off times in GMT.
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- Sat, Nov 17, 2012
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| FT | Aberdeen | 0 - 2 | Celtic |
| FT | Dundee | 3 - 1 | Hibernian |
| FT | Heart of Midlothian | 1 - 0 | St Mirren |
| FT | St Johnstone | 1 - 1 | Ross County |
| FT | Cowdenbeath | 1 - 1 | Airdrie United |
| FT | Dumbarton | 1 - 5 | Greenock Morton |
| FT | Livingston | 2 - 1 | Falkirk |
| FT | Raith Rovers | 1 - 3 | Dunfermline Athletic |
| FT | Albion Rovers | 0 - 3 | East Fife |
| FT | Alloa Athletic | 2 - 2 | Brechin City |
| FT | Arbroath | 2 - 3 | Queen of the South |
| FT | Ayr United | 2 - 1 | Stranraer |
| FT | Forfar Athletic | 3 - 2 | Stenhousemuir |
| FT | East Stirlingshire | 2 - 6 | Rangers |
| FT | Berwick Rangers | 3 - 1 | Annan Athletic |
| FT | Montrose | 1 - 1 | Queen's Park |
| FT | Peterhead | 1 - 0 | Clyde |
| FT | Stirling Albion | 1 - 4 | Elgin City |
| FT | Osasuna | 0 - 0 | Malaga |
| FT | Valencia | 2 - 1 | Espanyol |
| FT | Barcelona | 3 - 1 | Real Zaragoza |
| FT | Real Madrid | 5 - 1 | Athletic Bilbao |
| FT | Empoli | 3 - 2 | Grosseto |
| FT | Lanciano | 0 - 3 | Bari |
| FT | Livorno | 2 - 0 | Varese |
| FT | Modena | 1 - 1 | Ascoli |
| FT | Padova | 3 - 1 | Cittadella |
| FT | Pro Vercelli | 0 - 2 | Crotone |
| FT | Reggina | 1 - 1 | Ternana |
| FT | Spezia | 2 - 3 | Juve Stabia |
| FT | Vicenza | 2 - 1 | Novara |
| FT | Paris Saint-Germain | 1 - 2 | Stade Rennes |
| FT | AC Ajaccio | 0 - 1 | Sochaux |
| FT | Brest | 3 - 0 | Bastia |
| FT | Evian Thonon Gaillard | 2 - 2 | St Etienne |
| FT | Troyes | 3 - 3 | AS Nancy Lorraine |
| FT | Valenciennes | 1 - 1 | Montpellier |
| FT | ADO Den Haag | 1 - 6 | PSV Eindhoven |
| FT | Ajax Amsterdam | 2 - 0 | VVV Venlo |
| FT | Heerenveen | 0 - 2 | RKC Waalwijk |
| FT | PEC Zwolle | 2 - 0 | NAC Breda |
| FT | FC Groningen | 1 - 1 | AZ Alkmaar |
| FT | Volga Nizhny Novgorod | 1 - 1 | Spartak Moscow |
| Aban | Dinamo Moscow | 1 a 0 | Zenit St Petersburg |
| FT | Alania Vladikavkaz | 0 - 2 | FK Rubin Kazan |
| FT | Istanbul Buyuksehir BSK | 1 - 1 | Elazigspor |
| FT | Eskisehirspor K | 1 - 1 | Fenerbahce |
| FT | Genclerbirligi | 1 - 1 | Sivasspor |
| FT | Aris Salonika | 1 - 2 | Giannina |
| FT | Panionios | 4 - 0 | Platanias |
| FT | Olympiakos | 2 - 0 | Kerkyra |
| FT | Cercle Brugge KSV | 3 - 1 | Racing Genk |
| FT | Lierse SK | 2 - 0 | KAA Gent |
| FT | OH Leuven | 1 - 3 | RAEC Bergen Mons |
| FT | Royal Charleroi SC | 1 - 1 | KV Mechelen |
| FT | Waasland-Beveren | 2 - 6 | Club Brugge |
| FT | Austria Vienna | 3 - 0 | FC Magna Wr. Neustadt |
| FT | SK Sturm Graz | 3 - 1 | SV Josko Ried |
| FT | SV Mattersburg | 0 - 3 | Rapid Vienna |
| FT | Wolfsberger AC | 1 - 1 | FC Trenkwalder Admira |
| FT | Ballymena | 0 - 8 | Cliftonville |
| FT | Crusaders | 2 - 0 | Portadown |
| FT | Dungannon Swifts | 1 - 1 | Coleraine |
| FT | Linfield | 1 - 1 | Glenavon |
| FT | Lisburn Distillery | 0 - 2 | Glentoran |
| FT | Danubio F.C. | 0 - 2 | River Plate |
| FT | Defensor Sporting | 4 - 0 | Bella Vista |
| FT | Cerro Largo | 0 - 0 | Central Español |
| FT | Progreso | 1 - 3 | Peñarol |
| FT | Independiente CG | 2 - 2 | Rubio Ñú |
| FT | Nacional | 4 - 1 | Olimpia |
| FT | Sportivo Luqueño | 1 - 0 | Sol de América |
| FT | Libertad | 2 - 1 | Sp. Carapeguá |
| FT | Cerezo Osaka | 1 - 3 | Omiya Ardija |
| FT | Consadole Sapporo | 2 - 3 | Sagan Tosu |
| FT | FC Tokyo | 0 - 1 | Vissel Kobe |
| FT | Shimizu S-Pulse | 1 - 3 | Gamba Osaka |
| FT | Melbourne Victory | 2 - 2 | Central Coast Mariners |
| FT | Newcastle Jets | 0 - 3 | Wellington Phoenix FC |
| FT | Perth Glory | 0 - 1 | Western Sydney FC |
| FT | Alianza FC | 2 - 0 | Juventud Independiente |
| FT | Luis Angel Firpo | 3 - 2 | Universidad de El Salvador |
| FT | Metapan | 1 - 0 | Atletico Marte |
| FT | Once Municipal | 1 - 3 | CD FAS |
| FT | Santa Tecla | 1 - 3 | Aguila |