All kick-off times in GMT.
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- Thu, Nov 22, 2012
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| FT | San Martín de Tucumán | 3 - 1 | Atlético Famaillá |
| FT | Ctral. Córdoba SE | 2 - 0 | Sarmiento (SE) |
| FT | Juventud Antoniana | 3 - 0 | Américo Tesorieri (La Rioja) |
| FT | Gimnasia y Tiro (Orán) | 2 - 1 | Sp. Villa Cubas |
| FT | Juventud Unida (SL) | (1)2 - 2(3) | Sp. Atenas |
| FT | Deportivo Maipú | 1 - 2 | San Martín (M) |
| FT | Talleres de Córdoba | 3 - 1 | Gutiérrez SC |
| FT | Sp. Belgrano | 2 - 1 | Academia FC |
| FT | Gimnasia (CDU) | (3)2 - 2(2) | At. Paraná |
| FT | Racing (Cba) | 2 - 0 | At. Colegiales |
| FT | Racing (O) | 5 - 1 | Cruz del Sur |