All kick-off times in GMT.
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- Sat, Nov 24, 2012
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| FT | Sunderland | 2 - 4 | West Bromwich Albion |
| FT | Everton | 1 - 1 | Norwich City |
| FT | Manchester United | 3 - 1 | Queens Park Rangers |
| FT | Stoke City | 1 - 0 | Fulham |
| FT | Wigan Athletic | 3 - 2 | Reading |
| FT | Aston Villa | 0 - 0 | Arsenal |
| FT | Motherwell | 0 - 0 | Heart of Midlothian |
| FT | Celtic | 0 - 1 | Inverness Caledonian Thistle |
| FT | Hibernian | 0 - 1 | Aberdeen |
| FT | Kilmarnock | 1 - 2 | St Johnstone |
| FT | Ross County | 1 - 2 | Dundee United |
| FT | St Mirren | 3 - 1 | Dundee |
| FT | Airdrie United | 0 - 0 | Raith Rovers |
| FT | Dunfermline Athletic | 4 - 0 | Dumbarton |
| FT | Falkirk | 2 - 1 | Hamilton Academical |
| FT | Greenock Morton | 1 - 0 | Cowdenbeath |
| FT | Partick Thistle | 2 - 0 | Livingston |
| FT | Brechin City | 4 - 1 | Forfar Athletic |
| FT | East Fife | 2 - 1 | Arbroath |
| FT | Queen of the South | 2 - 0 | Ayr United |
| FT | Stenhousemuir | 0 - 2 | Alloa Athletic |
| FT | Stranraer | 1 - 1 | Albion Rovers |
| FT | Rayo Vallecano | 2 - 0 | Mallorca |
| FT | Real Valladolid | 1 - 0 | Granada |
| FT | Malaga | 4 - 0 | Valencia |
| FT | Real Betis | 1 - 0 | Real Madrid |
| FT | Girona | 0 - 1 | Elche |
| FT | Guadalajara | 1 - 0 | Recreativo Huelva |
| FT | Hercules | 1 - 1 | Sporting Gijon |
| FT | Las Palmas | 3 - 0 | Cordoba |
| FT | CD Sabadell | 1 - 1 | Mirandes |
| FT | Villarreal | 1 - 1 | Lugo |
| FT | Bayern Munich | 5 - 0 | Hannover 96 |
| FT | Mainz | 1 - 2 | Borussia Dortmund |
| FT | Schalke 04 | 1 - 1 | Eintracht Frankfurt |
| FT | SpVgg Greuther Furth | 0 - 0 | Nurnberg |
| FT | VfL Wolfsburg | 1 - 1 | Werder Bremen |
| FT | Energie Cottbus | 3 - 1 | TSV Eintracht Braunschweig |
| FT | FC Union Berlin | 2 - 2 | TSV 1860 Munich |
| FT | FSV Frankfurt | 0 - 1 | Kaiserslautern |
| FT | Paris Saint-Germain | 4 - 0 | Troyes |
| FT | AS Nancy Lorraine | 1 - 1 | AC Ajaccio |
| FT | Bastia | 2 - 1 | Lorient |
| FT | Sochaux | 0 - 1 | Nice |
| FT | Stade de Reims | 0 - 0 | Brest |
| FT | Stade Rennes | 0 - 1 | Evian Thonon Gaillard |
| FT | NEC Nijmegen | 2 - 0 | FC Utrecht |
| FT | RKC Waalwijk | 1 - 1 | FC Groningen |
| FT | VVV Venlo | 1 - 1 | Heerenveen |
| FT | Willem II Tilburg | 2 - 2 | SC Heracles Almelo |
| FT | Germinal Beerschot | 1 - 4 | Anderlecht |
| FT | KAA Gent | 0 - 1 | Zulte-Waregem |
| FT | KV Kortrijk | 3 - 1 | Cercle Brugge KSV |
| FT | KV Mechelen | 0 - 1 | Waasland-Beveren |
| FT | RAEC Bergen Mons | 1 - 2 | KSC Lokeren |
| FT | FC Wacker Tirol | 0 - 3 | SK Sturm Graz |
| FT | Austria Vienna | 3 - 1 | SV Mattersburg |
| FT | FC Magna Wr. Neustadt | 2 - 1 | Wolfsberger AC |
| FT | SV Josko Ried | 3 - 1 | SV Salzburg |
| FT | Coleraine | 1 - 0 | Glentoran |
| FT | Donegal Celtic | 2 - 5 | Crusaders |
| FT | Glenavon | 0 - 1 | Ballinamallard Utd |
| FT | Linfield | 2 - 1 | Ballymena |
| FT | Portadown | 1 - 1 | Dungannon Swifts |
| FT | Aberystwyth | 3 - 0 | Connah's Quay |
| FT | Afan Lido | 2 - 3 | Bangor City |
| FT | Airbus UK | 5 - 0 | Port Talbot |
| FT | Newtown | 1 - 1 | Llanelli |
| FT | Prestatyn Town | 1 - 0 | Bala Town |
| FT | T.N.S. | 0 - 3 | Carmarthen |
| FT | Independiente | 2 - 2 | River Plate |
| FT | Unión de Santa Fe | 2 - 2 | Newell's Old Boys |
| FT | San Martín de San Juan | 1 - 1 | Belgrano de Córdoba |
| FT | Argentinos Juniors | 1 - 2 | San Lorenzo |
| FT | Consadole Sapporo | 0 - 2 | Yokohama F. Marinos |
| FT | Kashiwa Reysol | 1 - 0 | Vissel Kobe |
| FT | Kawasaki Frontale | 2 - 1 | Shimizu S-Pulse |
| FT | Omiya Ardija | 2 - 0 | Jubilo Iwata |