All kick-off times in GMT.
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- Sun, Nov 25, 2012
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| FT | Swansea City | 0 - 0 | Liverpool |
| FT | Southampton | 2 - 0 | Newcastle United |
| FT | Chelsea | 0 - 0 | Manchester City |
| FT | Tottenham Hotspur | 3 - 1 | West Ham United |
| FT | Espanyol | 0 - 2 | Getafe |
| FT | Athletic Bilbao | 1 - 1 | Deportivo La Coruña |
| FT | Atletico Madrid | 4 - 0 | Sevilla FC |
| FT | Levante | 0 - 4 | Barcelona |
| FT | Barcelona B | 4 - 1 | Racing Santander |
| FT | Almeria | 3 - 2 | Murcia |
| FT | Ponferradina | 2 - 1 | Huesca |
| FT | Xerez | 2 - 4 | AD Alcorcon |
| FT | Real Madrid Castilla | 2 - 4 | Numancia |
| FT | Atalanta | 0 - 1 | Genoa |
| FT | Chievo Verona | 0 - 0 | Siena |
| FT | Sampdoria | 1 - 0 | Bologna |
| FT | Torino | 2 - 2 | Fiorentina |
| FT | US Pescara | 0 - 1 | AS Roma |
| FT | AC Milan | 1 - 0 | Juventus |
| FT | SC Freiburg | 3 - 0 | VfB Stuttgart |
| FT | FC Augsburg | 1 - 1 | Borussia Monchengladbach |
| FT | TSG Hoffenheim | 1 - 2 | Bayer Leverkusen |
| FT | FC Erzgebirge Aue | 0 - 4 | Hertha Berlin |
| FT | FC Ingolstadt 04 | 1 - 1 | SV Sandhausen |
| FT | St Pauli | 4 - 1 | MSV Duisburg |
| FT | Roda JC Kerkrade | 1 - 2 | Ajax Amsterdam |
| FT | AZ Alkmaar | 0 - 2 | Feyenoord Rotterdam |
| FT | PSV Eindhoven | 1 - 2 | Vitesse Arnhem |
| FT | Twente Enschede | 2 - 2 | PEC Zwolle |
| FT | CD Nacional de Madeira | 1 - 0 | Estoril |
| FT | Vitoria Setubal | 3 - 5 | Rio Ave |
| FT | Academica de Coimbra | 2 - 2 | Gil Vicente |
| FT | Braga | 0 - 2 | FC Porto |
| FT | Bursaspor | 1 - 1 | Antalyaspor |
| FT | Elazigspor | 0 - 1 | Galatasaray |
| FT | Fenerbahce | 4 - 1 | Genclerbirligi |
| FT | Gaziantepspor | 2 - 1 | Istanbul Buyuksehir BSK |
| FT | Kasimpasa | 1 - 1 | Orduspor |
| FT | Sivasspor | 4 - 2 | Kayserispor |
| FT | Kerkyra | 1 - 1 | Veria |
| FT | Asteras Tripoli | 2 - 1 | Panionios |
| FT | Platanias | 2 - 1 | Panathinaikos |
| FT | PAOK Salonika | 1 - 1 | Olympiakos |
| FT | FC Trenkwalder Admira | 0 - 2 | Rapid Vienna |
| FT | FC Sion Sitten | 1 - 1 | Grasshoppers |
| FT | FC Thun | 3 - 2 | FC Basel |
| FT | FC Zürich | 0 - 2 | Servette |
| FT | St Gallen | 1 - 1 | Lucerne |
| FT | All Boys | 0 - 2 | Vélez Sarsfield |
| FT | Lanús | 0 - 0 | Estudiantes La Plata |
| FT | Tigre | 2 - 0 | Godoy Cruz de Mendoza |
| FT | Boca Juniors | 3 - 1 | Racing Club |
| FT | Bella Vista | 2 - 1 | Danubio F.C. |
| FT | Cerro | 0 - 2 | Central Español |
| FT | El Tanque Sisley | 2 - 2 | Liverpool |
| FT | Progreso | 0 - 1 | Juventud |
| FT | Wanderers | 1 - 2 | Peñarol |
| Group A | |||
|---|---|---|---|
| FT | Inti Gas Deportes | 2 - 0 | Cobresol |
| FT | José Gálvez | 3 - 0 | Universitario de Deportes |
| FT | San Martin | 2 - 0 | Sport Huancayo |
| FT | Sporting Cristal | 3 - 3 | Club Sportivo Cienciano |
| Group B | |||
| FT | Juan Aurich | 2 - 1 | Unión Comercio |
| FT | León de Huánuco | 3 - 0 | Sport Boys |
| FT | Melgar FBC | 2 - 0 | Alianza Lima |
| FT | Real Garcilaso | 1 - 1 | César Vallejo |
| FT | Cerro Porteño de Franco | 1 - 1 | Independiente CG |
| FT | Nacional | 2 - 0 | Sp. Carapeguá |
| FT | Sportivo Luqueño | 2 - 0 | Rubio Ñú |
| FT | Tacuary | 2 - 1 | Sol de América |
| FT | Libertad | 1 - 0 | Cerro Porteño |
| FT | El Nacional | 0 - 1 | Liga de Loja |
| FT | Emelec | 2 - 1 | Tec. Universitario |
| FT | Independiente Terán | 1 - 0 | Club Deportivo Cuenca |
| FT | Macará | 0 - 2 | Barcelona |
| FT | Manta F.C. | 4 - 1 | Deportivo Quito |
| FT | Olmedo | 0 - 1 | LDU Quito |
| FT | Dep. Petare | 1 - 2 | Zulia |
| FT | Deportivo Táchira | 2 - 1 | Portuguesa |
| FT | Llaneros | 2 - 1 | Atlético Vigía |
| FT | Trujillanos | 2 - 1 | Aragua |
| FT | Yaracuyanos | 0 - 2 | Caracas F.C. |
| FT | Estudiantes de Mérida | 1 - 4 | Atlético Venezuela |
| FT | Monagas SC | 2 - 2 | CD Lara |
| FT | A.C. Mineros | 0 - 2 | Anzoátegui |
| FT | Carmelita | 2 - 5 | Santos |
| FT | Cartagines | 1 - 1 | Alajuelense |
| FT | Club Sport Uruguay | 3 - 0 | Perez Zeledon |
| FT | Herediano | 1 - 0 | San Carlos |
| FT | Puntarenas | 3 - 2 | Belen |
| FT | Saprissa | 2 - 0 | Limon |
| FT | Aguila | 1 - 2 | Metapan |
| FT | Atletico Marte | 0 - 2 | Alianza FC |
| FT | CD FAS | 4 - 1 | Santa Tecla |
| FT | Juventud Independiente | 1 - 1 | Luis Angel Firpo |
| FT | Universidad de El Salvador | 2 - 1 | Once Municipal |
| FT | Marquense | 2 - 1 | Heredia |
| FT | Mictlan | 1 - 0 | Malacateco |
| FT | Municipal | 4 - 4 | Universidad de San Carlos |
| FT | Petapa | 2 - 0 | Penarol |
| FT | Suchitepequez | 4 - 2 | Juventud Escuintleca |
| FT | Xelaju | 1 - 2 | Comunicaciones |
| FT | CD Motagua | 1 - 1 | Victoria |
| FT | Atletico Choloma | 1 - 0 | Olimpia |