All kick-off times in GMT.
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- Sat, Dec 1, 2012
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| FT | Rochdale | 2 - 3 | York City |
| FT | Torquay United | 2 - 1 | Dagenham & Redbridge |
| FT | Wycombe Wanderers | 2 - 0 | Bristol Rovers |
| FT | Getafe | 1 - 0 | Malaga |
| FT | Valencia | 2 - 5 | Real Sociedad |
| FT | Barcelona | 5 - 1 | Athletic Bilbao |
| FT | Real Madrid | 2 - 0 | Atletico Madrid |
| FT | Lyon | 1 - 0 | Montpellier |
| FT | Bordeaux | 2 - 2 | Sochaux |
| FT | Evian Thonon Gaillard | 1 - 1 | AS Nancy Lorraine |
| FT | Lille | 0 - 0 | Bastia |
| FT | Nice | 2 - 1 | Paris Saint-Germain |
| FT | Valenciennes | 1 - 0 | Stade de Reims |
| FT | Twente Enschede | 2 - 0 | ADO Den Haag |
| FT | Feyenoord Rotterdam | 2 - 0 | RKC Waalwijk |
| FT | Willem II Tilburg | 3 - 1 | Heerenveen |
| FT | Ajax Amsterdam | 3 - 1 | PSV Eindhoven |
| FT | Dinamo Moscow | 3 - 0 | FK Rubin Kazan |
| FT | Alania Vladikavkaz | 0 - 1 | Lokomotiv Moscow |
| FT | Volga Nizhny Novgorod | 1 - 1 | Terek Grozny |
| FT | Anderlecht | 2 - 1 | Cercle Brugge KSV |
| FT | Club Brugge | 1 - 1 | KV Mechelen |
| FT | Lierse SK | 0 - 3 | RAEC Bergen Mons |
| FT | OH Leuven | 1 - 1 | KAA Gent |
| FT | Royal Charleroi SC | 2 - 0 | KV Kortrijk |
| FT | Zulte-Waregem | 0 - 0 | Germinal Beerschot |
| FT | Wolfsberger AC | 2 - 2 | FC Wacker Tirol |
| FT | Rapid Vienna | 4 - 3 | SV Josko Ried |
| FT | SK Sturm Graz | 3 - 1 | FC Magna Wr. Neustadt |
| FT | SV Mattersburg | 3 - 0 | FC Trenkwalder Admira |
| FT | Coleraine | 0 - 2 | Glenavon |
| FT | Crusaders | 2 - 1 | Dungannon Swifts |
| FT | Donegal Celtic | 1 - 0 | Ballymena |
| FT | Glentoran | 2 - 1 | Ballinamallard Utd |
| FT | Lisburn Distillery | 1 - 1 | Linfield |
| FT | Portadown | 3 - 3 | Cliftonville |
| FT | Afan Lido | 2 - 1 | Connah's Quay |
| FT | Carmarthen | 1 - 1 | Bala Town |
| FT | Port Talbot | 1 - 0 | Prestatyn Town |
| FT | Bangor City | 0 - 1 | T.N.S. |
| FT | Godoy Cruz de Mendoza | 0 - 0 | Quilmes |
| FT | Colón de Santa Fe | 3 - 1 | Argentinos Juniors |
| FT | Racing Club | 3 - 1 | All Boys |
| FT | Cerro | 2 - 0 | Bella Vista |
| FT | Defensor Sporting | 1 - 0 | Cerro Largo |
| FT | Wanderers | 1 - 1 | El Tanque Sisley |
| FT | Nacional | 6 - 1 | Progreso |