All kick-off times in GMT.
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- Sat, Dec 29, 2012
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| FT | Dartford | 1 - 1 | Cambridge United |
| FT | Lincoln City | 1 - 1 | Gateshead |
| FT | Southport | 0 - 1 | Hyde |
| FT | Stockport County | 2 - 2 | AFC Telford United |
| FT | Wrexham | 2 - 2 | Tamworth |
| FT | Dundee | 1 - 3 | Aberdeen |
| FT | Hibernian | 1 - 0 | Celtic |
| FT | Motherwell | 2 - 2 | Kilmarnock |
| FT | St Johnstone | 0 - 0 | Inverness Caledonian Thistle |
| FT | Airdrie United | 1 - 1 | Partick Thistle |
| FT | Falkirk | 3 - 4 | Dumbarton |
| FT | Greenock Morton | 4 - 2 | Dunfermline Athletic |
| FT | Raith Rovers | 2 - 2 | Cowdenbeath |
| FT | Arbroath | 2 - 1 | Albion Rovers |
| FT | Ayr United | 0 - 0 | Alloa Athletic |
| FT | Forfar Athletic | 3 - 2 | East Fife |
| FT | Stenhousemuir | 1 - 3 | Queen of the South |
| FT | Stranraer | 0 - 2 | Brechin City |
| FT | Queen's Park | 0 - 1 | Rangers |
| FT | Annan Athletic | 2 - 0 | Elgin City |
| FT | Clyde | 2 - 1 | Berwick Rangers |
| FT | Montrose | 3 - 2 | Stirling Albion |
| FT | Peterhead | 2 - 0 | East Stirlingshire |