All kick-off times in GMT.
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- Wed, Jan 2, 2013
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| FT | St Johnstone | 1 - 0 | Dundee |
| FT | Aberdeen | 2 - 2 | Dundee United |
| FT | Celtic | 1 - 0 | Motherwell |
| FT | St Mirren | 1 - 1 | Kilmarnock |
| FT | Airdrie United | 1 - 1 | Cowdenbeath |
| FT | Dunfermline Athletic | 1 - 0 | Raith Rovers |
| FT | Greenock Morton | 0 - 3 | Dumbarton |
| FT | Albion Rovers | 2 - 3 | Stranraer |
| FT | Alloa Athletic | 1 - 0 | Stenhousemuir |
| FT | Arbroath | 1 - 0 | East Fife |
| FT | Ayr United | 1 - 5 | Queen of the South |
| FT | Forfar Athletic | 1 - 4 | Brechin City |
| FT | Annan Athletic | 1 - 3 | Rangers |
| FT | East Stirlingshire | 1 - 1 | Stirling Albion |
| FT | Elgin City | 0 - 3 | Peterhead |
| FT | Montrose | 1 - 3 | Berwick Rangers |
| FT | Queen's Park | 4 - 1 | Clyde |