All kick-off times in GMT.
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- Sun, Jan 6, 2013
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| FT | Celta Vigo | 3 - 1 | Real Valladolid |
| FT | Real Madrid | 4 - 3 | Real Sociedad |
| FT | Barcelona | 4 - 0 | Espanyol |
| FT | Mallorca | 1 - 1 | Atletico Madrid |
| FT | Girona | 0 - 1 | Almeria |
| FT | Murcia | 2 - 1 | Hercules |
| FT | Elche | 3 - 2 | CD Sabadell |
| FT | Lugo | 0 - 0 | Guadalajara |
| FT | Mirandes | 0 - 0 | Cordoba |
| FT | Numancia | 3 - 0 | Las Palmas |
| FT | Xerez | 1 - 1 | Huesca |
| FT | Udinese | 3 - 0 | Internazionale |
| FT | AC Milan | 2 - 1 | Siena |
| FT | Chievo Verona | 1 - 0 | Atalanta |
| FT | Fiorentina | 0 - 2 | US Pescara |
| FT | Genoa | 2 - 0 | Bologna |
| FT | Juventus | 1 - 2 | Sampdoria |
| FT | Parma | 2 - 1 | Palermo |
| FT | Napoli | 4 - 1 | AS Roma |
| FT | Bourg-Peronnas | 1 - 2 | Montpellier |
| FT | Muret | 0 - 2 | Fontenay Foot |
| FT | Caen | 2 - 3 | St Etienne |
| FT | Chateauroux | 2 - 3 | Bordeaux |
| FT-Pens | Epinal | (4)3 - 3(2) | Lyon |
| FT | Lens | 2 - 1 | Stade Rennes |
| FT | Marseille | 2 - 1 | Guingamp |
| FT | Metz | 2 - 3 | Nice |
| FT | Meaux | 1 - 0 | Le Portel |
| FT | Avenir Foot Lozere | 2 - 0 | Arles |
| FT | Pontarlier | 1 - 2 | Sedan |
| FT-Pens | Lucon | (2)1 - 1(4) | Brest |
| FT | Bastia CA | 2 - 0 | Bastia |
| FT | Dieppe | 2 - 3 | Nantes |
| FT | Arras | 3 - 4 | Paris Saint-Germain |