All kick-off times in GMT.
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- Wed, Jan 23, 2013
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| FT-Pens | Nice | (2)2 - 2(4) | AS Nancy Lorraine |
| FT | Montpellier | 2 - 3 | Sochaux |
| FT | Raon-l'Etape | 1 - 0 | FC Istres |
| FT-Pens | Meaux | (3)0 - 0(5) | St Etienne |
| FT-Pens | Venissieux Minguettes | (4)0 - 0(3) | Le Poire SV |
| FT | Bastia CA | 1 - 3 | Brest |
| FT | Bordeaux Stade | 0 - 3 | Lens |
| FT | Moulins | 1 - 2 | Bordeaux |
| FT | Paris Saint-Germain | 3 - 1 | Toulouse |
| FT | Cruzeiro POA | 0 - 0 | Santa Cruz |
| FT | Cerámica | 1 - 2 | Internacional |
| FT | Novo Hamburgo | 0 - 2 | São José-POA |
| FT | Passo Fundo | 1 - 1 | Juventude |
| FT | Pelotas | 1 - 3 | Esportivo-RS |
| Group A | |||
|---|---|---|---|
| FT | Madureira | 1 - 1 | Flamengo |
| FT | Audax Rio | 2 - 1 | Nova Iguaçu |
| FT | Quissama | 0 - 0 | Resende |
| FT | Duque de Caxias | 1 - 2 | Friburguense |
| FT | CR Vasco da Gama | 4 - 2 | Macaé |
| FT | Bragantino | 2 - 2 | Linense |
| FT | Corinthians | 0 - 1 | AA Ponte Preta |
| FT | Guarani SP | 0 - 0 | Sao Bernardo |
| FT | Ituano | 0 - 0 | Atlético Sorocaba |
| FT | Santos FC | 3 - 0 | Botafogo (RP) |
| FT | Oeste | 1 - 3 | Palmeiras |