All kick-off times in GMT.
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- Sat, Feb 9, 2013
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| FT | Inverness Caledonian Thistle | 1 - 3 | Celtic |
| FT | Aberdeen | 0 - 0 | St Mirren |
| FT | Dundee United | 3 - 1 | Heart of Midlothian |
| FT | Kilmarnock | 2 - 0 | Motherwell |
| FT | Airdrie United | 0 - 4 | Greenock Morton |
| FT | Cowdenbeath | 4 - 1 | Falkirk |
| FT | Hamilton Academical | 1 - 2 | Dunfermline Athletic |
| FT | Livingston | 2 - 3 | Dumbarton |
| FT | Albion Rovers | 0 - 1 | Arbroath |
| FT | Alloa Athletic | 2 - 2 | Ayr United |
| FT | East Fife | 1 - 2 | Forfar Athletic |
| FT | Queen of the South | 2 - 1 | Stenhousemuir |
| FT | Berwick Rangers | 3 - 3 | Clyde |
| FT | East Stirlingshire | 2 - 4 | Peterhead |
| FT | Elgin City | 3 - 1 | Annan Athletic |
| FT | Rangers | 4 - 0 | Queen's Park |
| FT | Stirling Albion | 3 - 1 | Montrose |
| FT | Mallorca | 1 - 1 | Osasuna |
| FT | Celta Vigo | 0 - 1 | Valencia |
| FT | Levante | 1 - 2 | Malaga |
| FT | Deportivo La Coruña | 0 - 3 | Granada |
| FT | Real Madrid | 4 - 1 | Sevilla FC |
| FT | St Etienne | 4 - 1 | Montpellier |
| FT | AC Ajaccio | 1 - 0 | Bordeaux |
| FT | AS Nancy Lorraine | 1 - 2 | Stade de Reims |
| FT | Nice | 1 - 1 | Lorient |
| FT | Troyes | 0 - 0 | Sochaux |
| FT | Valenciennes | 2 - 1 | Brest |
| FT | ADO Den Haag | 2 - 1 | NAC Breda |
| FT | FC Groningen | 2 - 1 | RKC Waalwijk |
| FT | Heerenveen | 2 - 2 | VVV Venlo |
| FT | SC Heracles Almelo | 4 - 1 | Willem II Tilburg |
| FT | Vitesse Arnhem | 2 - 2 | PSV Eindhoven |
| FT | Istanbul Buyuksehir BSK | 0 - 2 | Akhisar Belediye |
| FT | Genclerbirligi | 0 - 2 | Eskisehirspor K |
| FT | Elazigspor | 1 - 3 | Besiktas |
| FT | Karabukspor | 0 - 3 | Bursaspor |
| FT | Germinal Beerschot | 0 - 2 | Racing Genk |
| FT | Club Brugge | 3 - 1 | OH Leuven |
| FT | KSC Lokeren | 1 - 1 | Zulte-Waregem |
| FT | KV Kortrijk | 1 - 0 | KAA Gent |
| FT | KV Mechelen | 2 - 0 | Cercle Brugge KSV |
| FT | Royal Charleroi SC | 1 - 0 | Lierse SK |
| FT | All Boys | 1 - 1 | Godoy Cruz de Mendoza |
| FT | Estudiantes La Plata | 1 - 3 | Tigre |
| FT | Boca Juniors | 3 - 2 | Quilmes |
| FT | San Martín de San Juan | 0 - 0 | San Lorenzo |
| FT | Cruz Azul | 1 - 1 | UNAM |
| FT | Querétaro | 1 - 1 | Chiapas |
| FT | Monterrey | 0 - 1 | Guadalajara |
| FT | Tijuana | 1 - 2 | América |
| FT | Atlas | 2 - 1 | Atlante |
| FT | San Luis | 1 - 3 | Puebla |
| FT | Municipal Iquique | 2 - 1 | Colo Colo |
| FT | Universidad de Chile | 0 - 3 | Unión Española |
| FT | Santiago Wanderers | 3 - 4 | Unión La Calera |
| FT | Atlético Huila | 1 - 1 | Itagüí |
| FT | Boyacá Chicó FC | 1 - 2 | Deportivo Cali |
| FT | Independiente Santa Fe | 2 - 2 | Atlético Nacional |
| FT | Once Caldas | 2 - 1 | Atlético Junior |
| FT | Inti Gas Deportes | 2 - 0 | León de Huánuco |
| FT | Sporting Cristal | 1 - 0 | San Martin |
| FT | Universitario de Deportes | 1 - 0 | César Vallejo |
| FT | Pacífico FC | 1 - 0 | Juan Aurich |
| FT | Sol de América | 4 - 1 | Cerro Porteño |
| FT | Nacional | 4 - 3 | Sp. Carapeguá |
| FT | Guaraní | 1 - 1 | Libertad |
| FT | Malacateco | 5 - 0 | Juventud Escuintleca |
| FT | Comunicaciones | 1 - 0 | Heredia |
| FT | Petapa | 1 - 1 | Suchitepequez |
| FT | Xelaju | 2 - 0 | Mictlan |
| FT | Marathon | 0 - 0 | Real Espana |
| FT | Deportes Savio | 3 - 1 | C.D.Real Sociedad |