All kick-off times in GMT.
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- Tue, Feb 12, 2013
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| FT | Brighton & Hove Albion | 1 - 1 | Blackburn Rovers |
| FT | Hull City | 2 - 1 | Derby County |
| FT | Middlesbrough | 1 - 0 | Leeds United |
| Group 1 | |||
|---|---|---|---|
| FT | Nacional | 2 - 2 | Barcelona |
| Group 4 | |||
| FT | Emelec | 1 - 0 | Vélez Sarsfield |
| Group 7 | |||
| FT | Universidad de Chile | 2 - 0 | CD Lara |
| FT | San Martín de San Juan | (2)0 - 0(4) | At. Unión (SJ) |