All kick-off times in GMT.
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- Wed, Feb 13, 2013
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| Group 1 | |||
|---|---|---|---|
| FT | Boca Juniors | 1 - 2 | Toluca |
| Group 3 | |||
| FT | Atlético MG | 2 - 1 | São Paulo |
| Group 4 | |||
| FT | Municipal Iquique | 1 - 2 | Peñarol |
| Group 6 | |||
| FT | Real Garcilaso | 1 - 1 | Independiente Santa Fe |
| Group 8 | |||
| FT | Caracas F.C. | 0 - 1 | Fluminense FC |
| FT | Ajax Cape Town | 1 - 1 | Moroka Swallows |
| FT | Orlando Pirates | 1 - 0 | SuperSport United |
| FT | Pretoria Univ | 0 - 2 | Golden Arrows |
| FT | Silver Stars | 2 - 0 | Bloem Celtic |