All kick-off times in GMT.
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- Sun, Feb 17, 2013
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| FT | Real Sociedad | 1 - 1 | Levante |
| FT | Valencia | 2 - 0 | Mallorca |
| FT | Real Valladolid | 0 - 3 | Atletico Madrid |
| FT | Espanyol | 1 - 0 | Real Betis |
| FT | Real Madrid | 2 - 0 | Rayo Vallecano |
| FT | Recreativo Huelva | 1 - 0 | Racing Santander |
| FT | Sporting Gijon | 0 - 2 | Elche |
| FT | Cordoba | 1 - 1 | AD Alcorcon |
| FT | Huesca | 3 - 0 | Lugo |
| FT | Las Palmas | 5 - 2 | Girona |
| FT | Mirandes | 0 - 1 | Murcia |
| FT | Numancia | 3 - 0 | Xerez |
| FT | Hercules | 1 - 1 | Villarreal |
| FT | Catania | 1 - 0 | Bologna |
| FT | Genoa | 1 - 0 | Udinese |
| FT | Napoli | 0 - 0 | Sampdoria |
| FT | Torino | 2 - 1 | Atalanta |
| FT | US Pescara | 0 - 2 | Cagliari |
| FT | Fiorentina | 4 - 1 | Internazionale |
| FT | Dynamo Dresden | 3 - 1 | SV Sandhausen |
| FT | FSV Frankfurt | 1 - 0 | Energie Cottbus |
| FT | MSV Duisburg | 0 - 0 | Kaiserslautern |
| FT | Vitesse Arnhem | 2 - 0 | FC Groningen |
| FT | ADO Den Haag | 2 - 1 | Heerenveen |
| FT | PEC Zwolle | 3 - 2 | Feyenoord Rotterdam |
| FT | RKC Waalwijk | 0 - 2 | Ajax Amsterdam |
| FT | Maritimo | 2 - 1 | Estoril |
| FT | Olhanense | 0 - 1 | Vitoria Setubal |
| FT | Paços de Ferreira | 1 - 1 | CD Nacional de Madeira |
| FT | Guimaraes | 1 - 0 | Moreirense |
| FT | Benfica | 1 - 0 | Academica de Coimbra |
| FT | Genclerbirligi | 3 - 1 | Mersin Idmanyurdu |
| FT | Orduspor | 2 - 2 | Istanbul Buyuksehir BSK |
| FT | Bursaspor | 1 - 0 | Elazigspor |
| FT | Trabzonspor | 0 - 3 | Fenerbahce |
| FT | Levadiakos | 0 - 0 | Atromitos |
| FT | FC Xanthi | 0 - 2 | Olympiakos |
| FT | Veria | 1 - 2 | Asteras Tripoli |
| FT | Aris Salonika | 1 - 0 | Panathinaikos |
| FT | Tigre | 0 - 0 | Boca Juniors |
| FT | Quilmes | 2 - 1 | All Boys |
| FT | Newell's Old Boys | 0 - 3 | Lanús |
| FT | River Plate | 1 - 0 | Estudiantes La Plata |
| FT | Itagüí | 4 - 0 | Independiente Santa Fe |
| FT | Deportes Tolima | 2 - 2 | Once Caldas |
| FT | La Equidad | 1 - 0 | Independiente Medellín |
| FT | Deportivo Cali | 2 - 2 | Deportivo Pasto |
| FT | Juan Aurich | 2 - 1 | Melgar FBC |
| FT | León de Huánuco | 2 - 0 | UTC |
| FT | Club Sportivo Cienciano | 0 - 1 | Real Garcilaso |
| FT | San Martin | 0 - 0 | Universitario de Deportes |
| FT | César Vallejo | 3 - 1 | Unión Comercio |
| FT | Atlético Venezuela | 3 - 3 | Portuguesa |
| FT | Zulia | 1 - 1 | CD Lara |
| FT | Dep. Petare | 1 - 1 | Zamora |
| FT | Llaneros | 3 - 1 | Estudiantes de Mérida |
| FT | Monagas SC | 0 - 1 | Real Espor |
| FT | Yaracuyanos | 1 - 0 | Trujillanos |
| FT | Aragua | 0 - 1 | Anzoátegui |
| FT | Deportivo Táchira | 0 - 1 | A.C. Mineros |
| FT | La Paz | 0 - 1 | Wilstermann |
| FT | Petrolero | 1 - 4 | Bolívar |
| FT | Real Potosí | 3 - 1 | Nacional Potosí |
| FT | Aurora | 1 - 1 | Universitario de Sucre |
| FT | The Strongest | 3 - 1 | Blooming |
| FT | Oriente Petrolero | 3 - 2 | San José |
| FT | Chippa United | 3 - 1 | Black Leopards |
| FT | Perez Zeledon | 2 - 0 | Herediano |
| FT | Puntarenas | 1 - 0 | Club Sport Uruguay |
| FT | Limon | 0 - 2 | San Carlos |
| FT | Cartagines | 0 - 0 | Santos |
| FT | Alajuelense | 3 - 1 | Saprissa |
| FT | Mictlan | 1 - 0 | Marquense |
| FT | Municipal | 0 - 1 | Xelaju |
| FT | Heredia | 2 - 0 | Universidad |
| FT | Juventud Escuintleca | 3 - 1 | Petapa |
| FT | Penarol | 2 - 0 | Malacateco |