All kick-off times in GMT.
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- Wed, Feb 20, 2013
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| FT | SV Josko Ried | 1 - 1 | Wolfsberger AC |
| Group 4 | |||
|---|---|---|---|
| FT | Vélez Sarsfield | 3 - 0 | Municipal Iquique |
| Group 5 | |||
| FT | San José | 1 - 1 | Corinthians |
| Group 8 | |||
| FT | Huachipato | 1 - 3 | Caracas F.C. |
| FT | Fluminense FC | 0 - 3 | Gremio |
| FT | Defensa y Justicia | 0 - 3 | Estudiantes de Buenos Aires |
| FT | Colón de Santa Fe | 1 - 2 | Platense |
| FT | Rosario Central | 1 - 2 | Central Córdoba de Rosario |
| FT | Portuguesa | 0 - 0 | Zulia |
| FT | Real Espor | 1 - 0 | Deportivo Táchira |
| FT | Anzoátegui | 1 - 0 | Atlético Venezuela |
| FT | Dep. Petare | 0 - 0 | Llaneros |
| FT | Trujillanos | 1 - 0 | Monagas SC |
| FT | Estudiantes de Mérida | 1 - 0 | Yaracuyanos |
| FT | Zamora | 1 - 1 | Aragua |
| FT | Universitario de Sucre | 0 - 3 | Oriente Petrolero |
| FT | Nacional Potosí | 2 - 0 | Aurora |
| FT | Wilstermann | 1 - 1 | Real Potosí |