All kick-off times in GMT.
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- Thu, Feb 21, 2013
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| Group 2 | |||
|---|---|---|---|
| FT | Tigre | 0 - 2 | Libertad |
| Group 6 | |||
| FT | Cerro Porteño | 0 - 1 | Real Garcilaso |
| FT | Independiente Santa Fe | 1 - 1 | Deportes Tolima |
| Group 7 | |||
| FT | CD Lara | 2 - 1 | Newell's Old Boys |
| FT | Olimpo de Bahía Blanca | 2 - 1 | Guillermo Brown |