All kick-off times in GMT.
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- Tue, Feb 26, 2013
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| FT | Burnley | 0 - 1 | Huddersfield Town |
| FT | Leicester City | 3 - 0 | Blackburn Rovers |
| FT | Bolton Wanderers | 1 - 0 | Peterborough United |
| FT | Ascoli | 2 - 4 | Sassuolo |
| FT | Brescia | 0 - 3 | Empoli |
| FT | Grosseto | 1 - 2 | Vicenza |
| FT | Livorno | 1 - 2 | Crotone |
| FT | Modena | 2 - 2 | Lanciano |
| FT | Padova | 1 - 0 | Juve Stabia |
| FT | Pro Vercelli | 0 - 0 | Cittadella |
| FT | Reggina | 1 - 1 | Spezia |
| FT | Ternana | 1 - 1 | Novara |
| Group 3 | |||
|---|---|---|---|
| FT | Arsenal de Sarandí | 2 - 5 | Atlético MG |
| Group 4 | |||
| FT | Peñarol | 0 - 1 | Vélez Sarsfield |
| Group 5 | |||
| FT | Tijuana | 4 - 0 | San José |
| Group 6 | |||
| FT | Deportes Tolima | 0 - 1 | Real Garcilaso |
| FT | Vegalta Sendai | 1 - 1 | Provincial Electrical Authority |
| FT | FC Seoul | 4 - 0 | Jiangsu Shuntian |
| 11:00 | Pakhtakor Tashkent | v | Al-Ittifaq |
| FT | Guangzhou Evergrande | 1 - 0 | Urawa Red Diamonds |
| FT | Muang Thong United | 0 - 1 | Jeonbuk Motors |
| FT | Teraktor Sazi FC | 0 - 0 | Al-Jazeera |
| FT | Lekhwiya | 0 - 0 | Al-Shabab |
| FT | Al Shabab | 2 - 0 | El Jaish |