All kick-off times in GMT.
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- Wed, Feb 27, 2013
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| FT | Dundee | 2 - 2 | St Johnstone |
| FT | Hibernian | 2 - 2 | Kilmarnock |
| FT | Inverness Caledonian Thistle | 0 - 0 | Dundee United |
| FT | Motherwell | 2 - 1 | Celtic |
| FT | St Mirren | 2 - 0 | Heart of Midlothian |
| FT | Lorient | 3 - 0 | Brest |
| FT-Pens | Raon-l'Etape | (3)2 - 2(5) | Bordeaux |
| FT | Venissieux Minguettes | 0 - 2 | AS Nancy Lorraine |
| FT | Paris Saint-Germain | 2 - 0 | Marseille |
| FT | FC Wacker Tirol | 1 - 0 | FC Magna Wr. Neustadt |
| FT | Rapid Vienna | 1 - 1 | SK Sturm Graz |
| FT | SV Josko Ried | 1 - 3 | Austria Vienna |
| Group 1 | |||
|---|---|---|---|
| FT | Barcelona | 1 - 2 | Boca Juniors |
| Group 4 | |||
| FT | Municipal Iquique | 2 - 0 | Emelec |
| Group 5 | |||
| FT | Corinthians | 2 - 0 | Millonarios |
| Group 8 | |||
| FT | Huachipato | 1 - 2 | Fluminense FC |
| FT | Cartagines | 1 - 0 | Puntarenas |
| FT | Alajuelense | 1 - 1 | Club Sport Uruguay |
| FT | Perez Zeledon | 1 - 2 | Saprissa |
| FT | Alianza FC | 1 - 1 | Metapan |
| FT | Juv. Independiente | 1 - 2 | Luis Angel Firpo |
| FT | UES | 1 - 1 | Once Municipal |
| FT | Aguila | 1 - 4 | Atletico Marte |
| FT | CD FAS | 1 - 0 | Santa Tecla |
| FT | Municipal | 0 - 1 | Marquense |
| FT | Mictlan | 3 - 0 | Petapa |
| FT | Suchitepequez | 2 - 2 | Heredia |
| FT | Juventud Escuintleca | 2 - 1 | Universidad |
| FT | Xelaju | 0 - 1 | Malacateco |
| FT | CD Motagua | 1 - 1 | Victoria |
| FT | Deportes Savio | 1 - 1 | Olimpia |
| FT | Atletico Choloma | 0 - 0 | Marathon |
| FT | Real Espana | 1 - 0 | C.D.Real Sociedad |
| FT | Vida | 2 - 1 | Platense |