All kick-off times in GMT.
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- Sat, May 18, 2013
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| FT | Barcelona B | 1 - 1 | AD Alcorcon |
| FT | Las Palmas | 0 - 0 | Recreativo Huelva |
| FT | Real Madrid Castilla | 3 - 1 | Lugo |
| FT | Xerez | 0 - 2 | Sporting Gijon |
| FT | Ponferradina | 1 - 1 | Numancia |
| FT | Villarreal | 4 - 1 | Girona |
| FT | Cordoba | 2 - 2 | Huesca |
| FT | CSKA Moscow | 0 - 0 | Kuban Krasnodar |
| FT | Mordovia Saransk | 1 - 1 | Terek Grozny |
| FT | Krasnodar | 0 - 1 | Spartak Moscow |
| FT | Istanbul Buyuksehir BSK | 1 - 2 | Kasimpasa |
| FT | Karabukspor | 3 - 2 | Fenerbahce |
| FT | Orduspor | 0 - 2 | Akhisar Belediye |
| FT | Galatasaray | 2 - 0 | Trabzonspor |
| FT | Wolfsberger AC | 0 - 0 | FC Trenkwalder Admira |
| FT | Austria Vienna | 3 - 1 | FC Magna Wr. Neustadt |
| FT | SV Mattersburg | 2 - 0 | Rapid Vienna |
| FT | SV Salzburg | 3 - 1 | FC Wacker Tirol |
| FT | Brommapojkarna | 1 - 1 | Syrianska FC |
| FT | Port Talbot | 0 - 1 | Bala Town |
| 62' | Toronto FC | 0 - 1 | Columbus |
| 23:00 | Vancouver Whitecaps | v | Portland Timbers |
| 23:30 | Philadelphia Union | v | Chicago |
| May 19, 00:30 | Houston | v | New England |
| May 19, 02:30 | San Jose | v | Colorado |
| May 19, 02:30 | Seattle Sounders FC | v | FC Dallas |
| FT | Atletico Rafaela | 0 - 2 | Estudiantes La Plata |
| FT | Godoy Cruz de Mendoza | 3 - 1 | Vélez Sarsfield |
| HT | Quilmes | 0 - 1 | Newell's Old Boys |
| 23:15 | Boca Juniors | v | Colón de Santa Fe |
| FT | Palestino | 1 - 2 | Unión Española |
| FT | Unión La Calera | 1 - 2 | Cobreloa |
| 1st | Antofagasta | 1 - 0 | Arica |
| 22' | Colo Colo | 2 - 0 | Cobresal |
| May 19, 00:30 | Santiago Wanderers | v | Ñublense |
| FT | Defensor Sporting | 2 - 2 | River Plate |
| FT | Central Español | 0 - 2 | Cerro |
| FT | Fénix | 3 - 1 | Cerro Largo |
| FT | Nacional | 1 - 1 | Racing (U) |
| FT | La Equidad | 1 - 1 | Deportivo Cali |
| 22:30 | Boyacá Chicó FC | v | Atlético Nacional |
| May 19, 00:45 | Deportes Tolima | v | Alianza Petrolera |
| May 19, 00:45 | Millonarios | v | Atlético Junior |
| FT | Cerro Porteño de Franco | 1 - 3 | Cerro Porteño |
| FT | Deportivo Capiatá | 3 - 4 | Rubio Ñú |
| FT | Sportivo Luqueño | 0 - 0 | General Díaz |
| HT | Libertad | 0 - 0 | Nacional |
| FT | Yokohama F. Marinos | 0 - 0 | Vegalta Sendai |
| FT | Omiya Ardija | 2 - 1 | Shonan Bellmare |
| FT | FC Tokyo | 2 - 0 | Shimizu S-Pulse |
| FT | Urawa Red Diamonds | 6 - 2 | Sagan Tosu |
| May 19, 00:35 | FC Kansas City | v | Boston Breakers |